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η5-Cyclopentadienylrhodium(I) complexes containing diphosphines and their reactions with the electrophiles H+ and Me+. Crystal and molecular structure of [Rh(η-C5H5)(CO)(Ph2PCH2PPh2)], a complex with a unidentate bis(diphenylphosphino)methane ligand
1983-01-01 Faraone, Felice; Bruno, Giuseppe; LO SCHIAVO, Sandra; Tresoldi, Giuseppe; Gabriella, Bombieri
Mono-, bi-, and tri-nuclear η-cyclopentadienyl-rhodium complexes obtained from [Rh2(η-C5H5)2(μ-CO)(CO)2]. Crystal structure of [{Rh(η-C5H5)(μ-CO)}3]·0.24Me2CO
1983-01-01 Faraone, Felice; LO SCHIAVO, Sandra; Bruno, Giuseppe; Piraino, Pasquale; Gabriella, Bombieri
Synthesis and crystal and molecular structure of [(η-C5H5)Rh(μ-CO)2Rh(PPh3)(η-C5H5)] an asymmetric bimetallic complex with a polar rhodium-rhodium bond
1983-01-01 Faraone, Felice; Bruno, Giuseppe; LO SCHIAVO, Sandra; Piraino, Pasquale; Gabriella, Bombieri
Mercury(II) chloride bridging two rhodium atoms. Preparation and X-ray crystal structure of [Rh2(η-C5H5)2(μ-CO)(μ-Ph2PCH2PPh2)(μ-HgCl2)]
1984-01-01 Faraone, Felice; LO SCHIAVO, Sandra; Bruno, Giuseppe; Gabriella, Bombieri
Synthesis and some reactions of binuclear η-cyclopentadienyl rhodium complexes containing bis(diphenylphosphino)methane and small molecules (CO, SO2, or SnCl2) as bridging ligands. Crystal and molecular structure of [Rh2(η-C5H5)2(μ-CO)(μ-Ph2PCH2PPh2)]
1984-01-01 Faraone, Felice; Bruno, Giuseppe; LO SCHIAVO, Sandra; Gabriella, Bombieri
Chemical oxidation of binuclear rhodium(I) complexes with silver salts. Synthesis and x-ray crystal structure of the paramagnetic Rh25+ formamidinate complex Rh2(Form)3(NO3)2
1985-01-01 Piraino, Pasquale; Bruno, Giuseppe; Nicolo', Francesco; Faraone, Felice; LO SCHIAVO, Sandra
Electrophilic attack of proton and [Au(PPh3)]+ on an electron-rich rhodium-rhodium bond. Synthesis and structural characterization of [Rh2(η-C5H5)2(μ-CO)(μ-H)(μ-Ph2PCH2PPh2)]+ and [Rh2(η-C5H5)2(μ-CO)(μ-AuPPh3)(μ-Ph2PCH2PPh2)]+
1985-01-01 LO SCHIAVO, Sandra; Bruno, Giuseppe; Nicolo', Francesco; Piraino, Pasquale; Faraone, Felice
Addition of silver electrophiles to an electron-rich rhodium-rhodium bond. Synthesis and x-ray crystal structure of the [Rh2(η-C5H5)2(μ-CO)(μ-Ph2PCH2PPh2)(μ-AgOPF2O)], a triangular rhodium-silver cluster with the difluorophosphate ion coordinated to the silver atom
1985-01-01 Giuseppe. Bruno;Sandra. Lo Schiavo;Pasquale. Piraino;Felice. Faraone
Synthesis of triangular rhodium-silver clusters by the addition of silver electrophiles to electron-rich rhodium-rhodium bonds. X-ray crystal structure of [Rh2(η-C5H5)2(μ-CO)(μ-Ph2PCH2PPh2) (μ-AgO2CCH3)]
1986-01-01 LO SCHIAVO, Sandra; Bruno, Giuseppe; Piraino, Pasquale; Faraone, Felice
Ligating properties of thionitrosoamines. IV. Cationic complexes of rhodium(I), rhodium(III), and ruthenium(II) containing N-thionitrosodimethylamine
1987-01-01 Giuseppe Tresoldi;Sergio Sergi;Sandra Lo Schiavo;Pasquale Piraino
Synthesis, x-ray crystal structure, and electrochemical properties of the dirhodium(4+) complex Rh2(form)4 (form = N,N'-di-p-tolylformamidinate anion)
1987-01-01 Piraino, Pasquale; Bruno, Giuseppe; LO SCHIAVO, Sandra; Franco, Laschi; Piero, Zanello
Chemical oxidation of binuclear rhodium(I) complexes with silver salts. Synthesis, x-ray crystal structure, and electrochemical properties of the rhodium [Rh24+] mixed-ligand complex Rh2(Form)2(O2CCF3)2(H2O)2.0.5C6H6 (Form = N,N'-di-p-tolylformamidinate anion)
1987-01-01 Piraino, Pasquale; Bruno, Giuseppe; Tresoldi, Giuseppe; LO SCHIAVO, Sandra; Piero, Zanello
Ligating properties of thionitrosoamines. III. Carbonyl complexes of rhodium(I) and rhodium(III) containing N-thionitrosodimethylamine
1987-01-01 Tresoldi, Giuseppe; Sergi, Sergio; LO SCHIAVO, Sandra; Piraino, Pasquale
Synthesis of triangular mixed-metal clusters by the addition of copper electrophiles to an electron-rich rhodium-rhodium bond. X-ray crystal structures of [Rh2(η-C5H5)2(μ-CO)(μ-Ph2PCH2PPh2)(μ-CuI)] and [Rh2(η-C5H5)2(μ-CO)(μ-Ph2PCH2PPh2)(μ-AgO2CCH3)]
1987-01-01 Bruno, Giuseppe; LO SCHIAVO, Sandra; Rotondo, Enrico; Piraino, Pasquale; Faraone, Felice
Additions and Corrections - Synthesis of triangular mixed-metal clusters by the addition of copper electrophiles to an electron-rich rhodium-rhodium bond. X-ray crystal structures of [Rh2(η-C5H5)2(μ-CO)(μ-Ph2PCH2PPh2)(μ-CuI)] and [Rh2(η-C5H5)2(μ-CO)(μ-Ph2PCH2PPh2)(μ-AgO2CCF3)] [Erratum to document cited in CA107(23):217829Q]
1988-01-01 Bruno, Giuseppe; LO SCHIAVO, Sandra; Rotondo, Enrico; Piraino, Pasquale; Faraone, Felice
Bi- and Polynuclear Complexes With Short-bite Ligands Bridging Metal Atoms. [(η5-c5h5)rh(μ-ch3o2cc2co2ch3)(μ-ph2ppy)rh(c0)(μ-cl)]2: Synthesis, X-ray Crystal Structure, Structural Dynamics, and Reactions With Co and So2
1989-01-01 Rotondo, Enrico; Schiavo, Sandra Lo; Bruno, Giuseppe; Arena, Carmela Grazia; Gobetto, Roberto; Faraone, Felice
Synthesis, Oxidative Addition, and Structural Studies of the Metal—Metal Bonded Bimetallic Complexes [(η5-C5H5)Rh(μ-CO)(μ-Ph2PC5H4N)M(CO)Cl] (M = Rh, Ir)
1989-01-01 Bruno, Giuseppe; Schiavo, Sandra Lo; Rotondo, Enrico; Arena, Carmela Grazia; Faraone, Felice
Synthesis of asymmetric dirhodium(4+) complexes. X-ray crystal structure of Rh2(form)3(NO3)(PPh3).0.5CH2Cl2 and Rh2(form)3(NO3)(C5H5N) (form = N,N'-di-p-tolylformamidinate)
1989-01-01 Piraino, Pasquale; Bruno, Giuseppe; Tresoldi, Giuseppe; LO SCHIAVO, Sandra; Nicolo', Francesco
Synthesis and crystal structure of the new near-linear Rh2Mo trinuclear complex [(η5-C5H5)Rh(μ-CO)-(μ-Ph2PC5H4N)Rh(CO)Mo(CO)3(η5-C5H5)]
1990-01-01 LO SCHIAVO, Sandra; Faraone, Felice; Maurizio, Lanfranchi; Antonio, Tiripicchio
Synthesis and NMR investigation of dirhodium(4+) formamidinate complexes containing 2-(diphenylphosphino)pyridine as a bridging ligand. X-ray crystal structure of the complex Rh2(form)2(μ-PPh2Py)2(O2CCF3)2 (form = N,N'-di-p-tolylformamidinate)
1991-01-01 Rotondo, Enrico; Bruno, Giuseppe; Nicolo', Francesco; LO SCHIAVO, Sandra; Piraino, Pasquale
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