[Ni(C13H22N4O)](ClO4) 2, Mr = 507·9, triclinic, P.1̄ a = 8·699 (1), b = 10·029 (1), c = 11·923 (1)Å, α=94·34 (3), β= 108·63 (4), γ= 96·10 (3)°, V= 973·4 (4) Å3, Z = 2, D x = 1·73 Mg m-3, Mo Kα, λ = 0·71069 Å, μ = 12·5 cm -1, F(000) = 524, T = 298 K, final R = 0.055 and wR = 0·061 for 2900 independent reflections [I > 3σ(1)]. The coordination polyhedron around Ni is an irregular square pyramid with the protonated saltrien [saltrien = 2-O--C6H 4CH=N(CH2)2NH(CH2) 2NH(CH2)2NH2] acting as tetradentate ligand through one O and three N atoms. © 1988 International Union of Crystallography.
The synthesis and structure of (N-{2-[2-(2-ammonioethylamino)ethylamino]ethyl}salicylideneaminato-O,N,N',N'')nickel(II) perchlorate
BRUNO, Giuseppe;NICOLO', Francesco;
1988-01-01
Abstract
[Ni(C13H22N4O)](ClO4) 2, Mr = 507·9, triclinic, P.1̄ a = 8·699 (1), b = 10·029 (1), c = 11·923 (1)Å, α=94·34 (3), β= 108·63 (4), γ= 96·10 (3)°, V= 973·4 (4) Å3, Z = 2, D x = 1·73 Mg m-3, Mo Kα, λ = 0·71069 Å, μ = 12·5 cm -1, F(000) = 524, T = 298 K, final R = 0.055 and wR = 0·061 for 2900 independent reflections [I > 3σ(1)]. The coordination polyhedron around Ni is an irregular square pyramid with the protonated saltrien [saltrien = 2-O--C6H 4CH=N(CH2)2NH(CH2) 2NH(CH2)2NH2] acting as tetradentate ligand through one O and three N atoms. © 1988 International Union of Crystallography.File in questo prodotto:
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