Two phases of (VO)2P2O7 (I) were prepd. in an aq. and org. medium, resp., and their activity towards the oxidn. of n-butane or 1-butene to maleic anhydride was studied. Disorder along the (020) cleavage plane of I increased the no. of active sites for n-butane activation but did not modify the nature of the active centers for the subsequent oxidn. of but-1-ene. X-ray diffraction anal. patterns of the catalysts were the same before and after catalysis. [on SciFinder(R)]
Structure sensitivity of the n-butane selective oxidation to maleic anhydride
CENTI, Gabriele;
1985-01-01
Abstract
Two phases of (VO)2P2O7 (I) were prepd. in an aq. and org. medium, resp., and their activity towards the oxidn. of n-butane or 1-butene to maleic anhydride was studied. Disorder along the (020) cleavage plane of I increased the no. of active sites for n-butane activation but did not modify the nature of the active centers for the subsequent oxidn. of but-1-ene. X-ray diffraction anal. patterns of the catalysts were the same before and after catalysis. [on SciFinder(R)]File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
