The study of furan synthesis from butadiene indicates that high selectivities in furan may be obtained only at low conversion and low oxygen/butadiene ratios. The max. yields of furan obtained are approx. 30%, suggesting a consecutive mechanism of malic anhydride synthesis from butadiene, with furan as the intermediate, and a ratio of rate consts. of the two consecutive reactions close to 1.0, which is confirmed also by the similar temps. of onset in butadiene and furan formation. [on SciFinder(R)]

Furan production by oxygen insertion in the 1,4 positions of butadiene on vanadium-phosphorus-oxygen-based catalysts

CENTI, Gabriele;
1986-01-01

Abstract

The study of furan synthesis from butadiene indicates that high selectivities in furan may be obtained only at low conversion and low oxygen/butadiene ratios. The max. yields of furan obtained are approx. 30%, suggesting a consecutive mechanism of malic anhydride synthesis from butadiene, with furan as the intermediate, and a ratio of rate consts. of the two consecutive reactions close to 1.0, which is confirmed also by the similar temps. of onset in butadiene and furan formation. [on SciFinder(R)]
1986
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11570/1907371
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 29
  • ???jsp.display-item.citation.isi??? ND
social impact