The polarog. redn. in an aprotic solvent (DMF) of a series of sulfonamideand sulfanilamide derivs. is discussed in the light of CNDO/2 calcns. The main results are: (1) a realation between the half-wave potential and the energy of the LUMO; (2) the evidence of the C-S-N moiety as the electroactive center for the electron uptake; and (3) the preference of the S-N bondover the S-C bond for the reductive cleavage.
A theoretical study of a polarographic reduction of sulfanilmaide derivatives.
QUARTIERI, Simona;
1981-01-01
Abstract
The polarog. redn. in an aprotic solvent (DMF) of a series of sulfonamideand sulfanilamide derivs. is discussed in the light of CNDO/2 calcns. The main results are: (1) a realation between the half-wave potential and the energy of the LUMO; (2) the evidence of the C-S-N moiety as the electroactive center for the electron uptake; and (3) the preference of the S-N bondover the S-C bond for the reductive cleavage.File in questo prodotto:
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