Addition of [Mo(η5-C5H5)(CO)3]Na to a solution of the complex [η5-C5H5)Rh(μ-CO)(μ-Ph2PC5H4N)Rh(CO)Cl] (1) in THF results in the replacement of the terminal chloride by the anion [Mo(η5-C5H5)(CO)3]-, to give the near-linear trinuclear complex [(η5-C5H5)Rh(μ-CO)(μ-Ph2PC5H4N)Rh(CO)Mo(CO)3(η5-C5H5)] (3) in a good yield. The crystal structure of 3 has been determined by an X-ray diffraction study.
Synthesis and crystal structure of the new near-linear Rh2Mo trinuclear complex [(η5-C5H5)Rh(μ-CO)-(μ-Ph2PC5H4N)Rh(CO)Mo(CO)3(η5-C5H5)]
LO SCHIAVO, Sandra;FARAONE, Felice;
1990-01-01
Abstract
Addition of [Mo(η5-C5H5)(CO)3]Na to a solution of the complex [η5-C5H5)Rh(μ-CO)(μ-Ph2PC5H4N)Rh(CO)Cl] (1) in THF results in the replacement of the terminal chloride by the anion [Mo(η5-C5H5)(CO)3]-, to give the near-linear trinuclear complex [(η5-C5H5)Rh(μ-CO)(μ-Ph2PC5H4N)Rh(CO)Mo(CO)3(η5-C5H5)] (3) in a good yield. The crystal structure of 3 has been determined by an X-ray diffraction study.File in questo prodotto:
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