The asymmetric unit of the title complex, (C 6H 8N) 2[Cu(C 7H 3NO 4) 2]·6H2O, contains half a copper(II)-dipicolinate complex located on a twofold rotation axis, one protonated aniline mol-ecule and three solvent water mol-ecules. The Cu II atom is coordinated by four O atoms and two N atoms from two dipicolinate ligands in a distorted octa-hedral environment. In the crystal, the components are linked into a three-dimensional framework by inter-molecular O-H⋯O and N-H⋯O inter-actions.
Dianilinium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cuprate(II) hexahydrate
AMIRIRUDBARI, HADI;NICOLO', Francesco;
2012-01-01
Abstract
The asymmetric unit of the title complex, (C 6H 8N) 2[Cu(C 7H 3NO 4) 2]·6H2O, contains half a copper(II)-dipicolinate complex located on a twofold rotation axis, one protonated aniline mol-ecule and three solvent water mol-ecules. The Cu II atom is coordinated by four O atoms and two N atoms from two dipicolinate ligands in a distorted octa-hedral environment. In the crystal, the components are linked into a three-dimensional framework by inter-molecular O-H⋯O and N-H⋯O inter-actions.File in questo prodotto:
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