Structural, dynamical and optical properties of self-assembled uncharged porphyrin-based macromolecules were studied by Light Scattering and UV-vis Spectroscopy. The results show that size, rigidity of the formed aggregates, and the local arrangement of the macromolecules inside the aggregate strongly depend on the molecular architecture and on the position of the peripheral polyethylene oxide arms in the porphyrin structures.
Aggregation of porphyrin-based cyclic supramolecular architectures
CORSARO, CARMELO
2012-01-01
Abstract
Structural, dynamical and optical properties of self-assembled uncharged porphyrin-based macromolecules were studied by Light Scattering and UV-vis Spectroscopy. The results show that size, rigidity of the formed aggregates, and the local arrangement of the macromolecules inside the aggregate strongly depend on the molecular architecture and on the position of the peripheral polyethylene oxide arms in the porphyrin structures.File in questo prodotto:
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