The dielectric response of the different binary mixtures of 1,2-propanediol and glycerol have been measured in a spectral range covering nine decades of frequency while the temperature varies from room temperature down to the glass transition temperature T-g. The relationship between the fragility, the stretching parameter and the decoupling between the conductivity and the alpha relaxation times measured by their ratio, tau(sigma)/tau(chi), has been analysed and compared to the experimental data on m-toluidine
Fragility, stretching parameters and decoupling effect on some supercooled liquids
CUTRONI, Maria;MANDANICI, Andrea;
2002-01-01
Abstract
The dielectric response of the different binary mixtures of 1,2-propanediol and glycerol have been measured in a spectral range covering nine decades of frequency while the temperature varies from room temperature down to the glass transition temperature T-g. The relationship between the fragility, the stretching parameter and the decoupling between the conductivity and the alpha relaxation times measured by their ratio, tau(sigma)/tau(chi), has been analysed and compared to the experimental data on m-toluidineFile in questo prodotto:
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