Polycationic oxacalix[4]arene 1·4HCl was found to be able to recognise, in water, the neutral π-rich aromatic guest 2,7-dihydroxynaphthalene, despite earlier studies indicating that the binding cleft of the oxacalixarene is π rich in nature. 1H NMR titrations at different pH values demonstrate that the tricationic receptor 1·3H+ displays the highest affinity towards DHN. According to a combination of NMR data and semiempirical (PM6) calculations, hydrophobic interactions play a prominent role in the formation of the complex.
Hydrophobic interactions in the formation of a complex between a polycationic water-soluble oxacalix[4]arene and a neutral aromatic guest
MANGANARO, NADIA;LANDO, GABRIELE;PISAGATTI, Ilenia;NOTTI, Anna;PARISI, Melchiorre;GATTUSO, Giuseppe
2016-01-01
Abstract
Polycationic oxacalix[4]arene 1·4HCl was found to be able to recognise, in water, the neutral π-rich aromatic guest 2,7-dihydroxynaphthalene, despite earlier studies indicating that the binding cleft of the oxacalixarene is π rich in nature. 1H NMR titrations at different pH values demonstrate that the tricationic receptor 1·3H+ displays the highest affinity towards DHN. According to a combination of NMR data and semiempirical (PM6) calculations, hydrophobic interactions play a prominent role in the formation of the complex.File in questo prodotto:
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