The polaron theory of electrons solvated in molten salts is applied to dilute solutions of Cs in molten Csl. Structural and thermodynamic properties of the excess electron and of the surrounding liquid are calculated as well as the electronic absorption spectrum which is compared with the result of optical studies. The influence of the electron-cation attraction on the electron localization is discussed within the model considered.
EXCESS ELECTRONS IN MOLTEN-SALTS - POLARON THEORY OF DILUTE CS-CSI SOLUTIONS
MALESCIO, Gianpietro
1990-01-01
Abstract
The polaron theory of electrons solvated in molten salts is applied to dilute solutions of Cs in molten Csl. Structural and thermodynamic properties of the excess electron and of the surrounding liquid are calculated as well as the electronic absorption spectrum which is compared with the result of optical studies. The influence of the electron-cation attraction on the electron localization is discussed within the model considered.File in questo prodotto:
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