Opposite influence of calf thymus DNA on the rate of substitution of ethylenediamine, by thiourea, in the complex cations [Pd(bpy)(en)](2+) and [Pd(bromazepam)(en)](2+) (bromazepam=7-bromo-1,3-dihydro-5-(2-pyridyl)-2H-1,4- benzodiazepin-2-one)