Cyclohexylsulfinyl-3-methyl-1,3-butadienes 5, 6, and 1-[1-(cyclohexylsulfinyl)ethenyl]cyclohexene (7), easily prepared from cyclohexanethiol (1) via transient cyclohexanesuffenic acid (4), were reacted with N-phenylinaleimide under different conditions, at normal and high pressure. The stereochemical outcome of these cycloadditions contributes a better understanding of the relationships among different factors controlling facial diastereoselection.
Maleimide cycloadditions by sulfinyldienes: is the sulfur configuration the only controller of the diastereofacial selectivity?
AVERSA, Maria Chiara;BARATTUCCI, Anna;BONACCORSI, Paola Maria;
2005-01-01
Abstract
Cyclohexylsulfinyl-3-methyl-1,3-butadienes 5, 6, and 1-[1-(cyclohexylsulfinyl)ethenyl]cyclohexene (7), easily prepared from cyclohexanethiol (1) via transient cyclohexanesuffenic acid (4), were reacted with N-phenylinaleimide under different conditions, at normal and high pressure. The stereochemical outcome of these cycloadditions contributes a better understanding of the relationships among different factors controlling facial diastereoselection.File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
