In the solid state, a non-luminescent platinum(II) dithiooxamide species adsorbs gaseous HCl, yielding a tight ion pair species which exhibits photoluminescence; the process is quantitatively reversed on heating or by exposing the sample to ammonia vapors.
Solid-state luminescence switching of platinum(II) dithiooxamide complexes in the presence of hydrogen halide and amine gases
NASTASI, FRANCESCO;PUNTORIERO, Fausto;PALMERI, NATALE;CAVALLARO, Stefano;CAMPAGNA, Sebastiano;LANZA, Santo
2007-01-01
Abstract
In the solid state, a non-luminescent platinum(II) dithiooxamide species adsorbs gaseous HCl, yielding a tight ion pair species which exhibits photoluminescence; the process is quantitatively reversed on heating or by exposing the sample to ammonia vapors.File in questo prodotto:
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