A chemical device using a reaction of acetic anhydride as a source of thermal energy enabled us, without the need of a physical temperature programmer, to carry out a variable-temperature kinetic experiment and obtain, in a single run, the activation parameters of a reaction. Molecular temperature programmers of this kind are also proposed for the automatic determination of the dependence of thermodynamic parameters on the temperature.
Towards Molecular Temperature Programmers for Variable-Temperature Kinetic Experiments
ALIBRANDI, Giuseppe;LISTER, David George;LO VECCHIO, CARMELO
2009-01-01
Abstract
A chemical device using a reaction of acetic anhydride as a source of thermal energy enabled us, without the need of a physical temperature programmer, to carry out a variable-temperature kinetic experiment and obtain, in a single run, the activation parameters of a reaction. Molecular temperature programmers of this kind are also proposed for the automatic determination of the dependence of thermodynamic parameters on the temperature.File in questo prodotto:
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