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EnglishIn the title compound, [Hg(C(14)H(13)N(4)O(3))(2)], the central Hg atom (site symmetry 2) is six-coordinated by two tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl) triazenide ligands through two N and one O atoms. The mononuclear complex molecules are connected into two parallel chains by intermolecular C-H center dot center dot center dot O hydrogen-bonding interactions. These chains are connected to each other by face-to-edge C-H center dot center dot center dot pi interactions between the CH of the ethoxy groups and the aromatic rings, resulting in a two-dimensional architecture in the ac plane.
| Titolo: | Bis[1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenido]mercury(II) |
| Autori: | |
| Data di pubblicazione: | 2010 |
| Rivista: | |
| Abstract: | In the title compound, [Hg(C(14)H(13)N(4)O(3))(2)], the central Hg atom (site symmetry 2) is six-coordinated by two tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl) triazenide ligands through two N and one O atoms. The mononuclear complex molecules are connected into two parallel chains by intermolecular C-H center dot center dot center dot O hydrogen-bonding interactions. These chains are connected to each other by face-to-edge C-H center dot center dot center dot pi interactions between the CH of the ethoxy groups and the aromatic rings, resulting in a two-dimensional architecture in the ac plane. |
| Handle: | http://hdl.handle.net/11570/1908869 |
| Appare nelle tipologie: | 14.a.1 Articolo su rivista |
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