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EnglishSpecial Section Dendrons composed of three functionalized cone calix[4]arene substructures covalently bound to rigid C-3-symmetric tris-anilino cores through amide linkages have been obtained by a divergent synthetic protocol involving the coupling of p-nitrocalix[4]arene butanoic acid 9 with tris(4-aminophenyl)amine (TAPA), 1,3,5-tris(4-aminophenyl)benzene (TAPB), and 2,4,6-tris(4-aminophenyl)-s-triazine (TAPT). Two different amidation procedures were used to generate the dodecanitro intermediates (through activation of acid 9 with PyBOP catalyst or transformation into its acid chloride). The final reduction to the title dodecaamino dendrons was smoothly carried out with H-2 and Raney-Ni catalyst.
| Titolo: | Amino Surface-Functionalized Tris(calix[4]arene) Dendrons with Rigid C3-Symmetric Propeller Cores |
| Autori: | |
| Data di pubblicazione: | 2011 |
| Rivista: | |
| Abstract: | Special Section Dendrons composed of three functionalized cone calix[4]arene substructures covalently bound to rigid C-3-symmetric tris-anilino cores through amide linkages have been obtained by a divergent synthetic protocol involving the coupling of p-nitrocalix[4]arene butanoic acid 9 with tris(4-aminophenyl)amine (TAPA), 1,3,5-tris(4-aminophenyl)benzene (TAPB), and 2,4,6-tris(4-aminophenyl)-s-triazine (TAPT). Two different amidation procedures were used to generate the dodecanitro intermediates (through activation of acid 9 with PyBOP catalyst or transformation into its acid chloride). The final reduction to the title dodecaamino dendrons was smoothly carried out with H-2 and Raney-Ni catalyst. |
| Handle: | http://hdl.handle.net/11570/1914422 |
| Appare nelle tipologie: | 14.a.1 Articolo su rivista |
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