The serendipitous crystallization of a 1 : 1 endo-cavity complex between calix[5]arene penta-ester 1a and n-butylammonium ions sheds light on the conformational rearrangement—from cone-in to cone-out—this calixarene family undergoes upon guest inclusion.
Picturing the induced fit of calix[5]arenes upon n-alkylammonium cation binding
GATTUSO, Giuseppe;NOTTI, Anna;PARISI, Melchiorre;
2012-01-01
Abstract
The serendipitous crystallization of a 1 : 1 endo-cavity complex between calix[5]arene penta-ester 1a and n-butylammonium ions sheds light on the conformational rearrangement—from cone-in to cone-out—this calixarene family undergoes upon guest inclusion.File in questo prodotto:
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