CD and UV-vis measurements were carried out to demonstrate chirality induction—promoted by chiral covalently linked groups and non-covalently bound D- and K-[Ru(phen)3]2+ enantiomers—in metallo-porphyrin–calixarene and metallo-porphyrin–bis-calixarene non-covalent assemblies, respectively.
Induction of chirality in porphyrin-(bis)calixarene assemblies: a mixed covalent-non-covalent vs a fully non-covalent approach
GATTUSO, Giuseppe;NOTTI, Anna;PARISI, Melchiorre;
2012-01-01
Abstract
CD and UV-vis measurements were carried out to demonstrate chirality induction—promoted by chiral covalently linked groups and non-covalently bound D- and K-[Ru(phen)3]2+ enantiomers—in metallo-porphyrin–calixarene and metallo-porphyrin–bis-calixarene non-covalent assemblies, respectively.File in questo prodotto:
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