Nonfrontier charge-transfer interactions have been investigated for the cycloaddn. of diazomethane, 2-diazopropane and Me diazoacetate to a wide group of mono and disubstituted olefins. The main result is that these interactions, far from being negligible, play a decisive role in the rationalization of both the regiochem. and the rate of these reactions.
A quantitative analysis of the charge-transfer perturbation model for the cycloaddition of diazoalkanes with olefins
QUARTIERI, Simona;
1987-01-01
Abstract
Nonfrontier charge-transfer interactions have been investigated for the cycloaddn. of diazomethane, 2-diazopropane and Me diazoacetate to a wide group of mono and disubstituted olefins. The main result is that these interactions, far from being negligible, play a decisive role in the rationalization of both the regiochem. and the rate of these reactions.File in questo prodotto:
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