The title compound has been obtained by treating [Rh2(η- C5H5)2(μ-CO)(μ-dppm)] [dppm = bis(diphenylphosphino)-methane] with HgCl2, and characterized by spectroscopic and X-ray analyses; it represents the first example of mercury(II) chloride bridging two transition metal atoms in a complex.

Mercury(II) chloride bridging two rhodium atoms. Preparation and X-ray crystal structure of [Rh2(η-C5H5)2(μ-CO)(μ-Ph2PCH2PPh2)(μ-HgCl2)]

FARAONE, Felice;LO SCHIAVO, Sandra;BRUNO, Giuseppe;
1984-01-01

Abstract

The title compound has been obtained by treating [Rh2(η- C5H5)2(μ-CO)(μ-dppm)] [dppm = bis(diphenylphosphino)-methane] with HgCl2, and characterized by spectroscopic and X-ray analyses; it represents the first example of mercury(II) chloride bridging two transition metal atoms in a complex.
1984
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11570/2036438
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