The proton ionization in (Na, H)ClO4 0.1 M aqueous solution of cycloalkane- 1,1-dicarboxylic acids at 25°C was studied by means of potentiometric and calorimetric measurements. The thermodynamic functions pK, ΔG, ΔH and ΔS were obtained. The ΔS values were discussed in terms of solute-solvent interaction changes related to the conformational features of the acids
Thermodynamics of Cycloalkane-1,1-Dicarboxylic Acids in Aqueous Solution.
SAMMARTANO, Silvio
1975-01-01
Abstract
The proton ionization in (Na, H)ClO4 0.1 M aqueous solution of cycloalkane- 1,1-dicarboxylic acids at 25°C was studied by means of potentiometric and calorimetric measurements. The thermodynamic functions pK, ΔG, ΔH and ΔS were obtained. The ΔS values were discussed in terms of solute-solvent interaction changes related to the conformational features of the acidsFile in questo prodotto:
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