Experimental and calculation procedures for the study of weak complexes by the pH-measurement technique are described. An algorithm for the calculation of formation constants, together with a computer program in FORTRAN and BASIC versions, is reported. The problems of studying weak interactions are discussed. Simulated titration curves and experimental data for K+-thiodiacetate complexation were used to check the proposed method.
The Determination of Formation Constants of Weak Complexes by Potentiometric Measurements: Experimental Procedures and Calculation Methods
DE ROBERTIS, Alessandro;DE STEFANO, Concetta;SAMMARTANO, Silvio;
1987-01-01
Abstract
Experimental and calculation procedures for the study of weak complexes by the pH-measurement technique are described. An algorithm for the calculation of formation constants, together with a computer program in FORTRAN and BASIC versions, is reported. The problems of studying weak interactions are discussed. Simulated titration curves and experimental data for K+-thiodiacetate complexation were used to check the proposed method.File in questo prodotto:
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