The asymmetric unit of the title complex, (C 6H 8N) 2[Cu(C 7H 3NO 4) 2]¬∑6H2O, contains half a copper(II)-dipicolinate complex located on a twofold rotation axis, one protonated aniline mol-ecule and three solvent water mol-ecules. The Cu II atom is coordinated by four O atoms and two N atoms from two dipicolinate ligands in a distorted octa-hedral environment. In the crystal, the components are linked into a three-dimensional framework by inter-molecular O-H‚ãØO and N-H‚ãØO inter-actions.
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