We study a two-dimensional fluid of particles interacting through a spherically symmetric and marginally soft two-body repulsion. This model can exist in three different crystal phases, one of them with square symmetry and the other two triangular. We show that, while the triangular solids first melt into a hexatic fluid, the square solid is directly transformed on heating into an isotropic fluid through a first-order transition, with no intermediate tetratic phase. In the low-pressure triangular and square crystals, melting is reentrant provided the temperature is not too low, but without the neces- sity of two competing nearest-neighbor distances over a range of pressures. A whole spectrum of water-like fluid anomalies completes the picture for this model potential.
Hexatic phase and water-like anomalies in a two-dimensional fluid of particles with a weakly softened core
PRESTIPINO GIARRITTA, Santi;GIAQUINTA, Paolo Vittorio
2012-01-01
Abstract
We study a two-dimensional fluid of particles interacting through a spherically symmetric and marginally soft two-body repulsion. This model can exist in three different crystal phases, one of them with square symmetry and the other two triangular. We show that, while the triangular solids first melt into a hexatic fluid, the square solid is directly transformed on heating into an isotropic fluid through a first-order transition, with no intermediate tetratic phase. In the low-pressure triangular and square crystals, melting is reentrant provided the temperature is not too low, but without the neces- sity of two competing nearest-neighbor distances over a range of pressures. A whole spectrum of water-like fluid anomalies completes the picture for this model potential.Pubblicazioni consigliate
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