We evidenced the conversion of an unprecedented intermolecular bridged-proton bimetallic P-metallated phosphoryl complex [{[Ru](Ph2P=O)}(2)H][PF6](3) to its corresponding H-bonded water complex [{[Ru](Ph2P=O)}(2)(H2O)][PF6](2), a rare motif. Their synthesis, NMR data, X-ray crystal structures, electrochemical and photophysical properties are reported.
Evidence of the unprecedented conversion of intermolecular proton to water bridging of two phosphoryl ruthenium complexes
SANTORO, ANTONIO;PUNTORIERO, Fausto;CAMPAGNA, Sebastiano;
2013-01-01
Abstract
We evidenced the conversion of an unprecedented intermolecular bridged-proton bimetallic P-metallated phosphoryl complex [{[Ru](Ph2P=O)}(2)H][PF6](3) to its corresponding H-bonded water complex [{[Ru](Ph2P=O)}(2)(H2O)][PF6](2), a rare motif. Their synthesis, NMR data, X-ray crystal structures, electrochemical and photophysical properties are reported.File in questo prodotto:
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