The new 1D coordination polymer, [Cd(Clphtpy)(NCS)(NO3)] n (Clphtpy = 4'- chlorophenyl-2,2':6',2''-terpyridine), was prepared and characterized by CHN elemental analysis, 1H NMR-, IR spectroscopy and analyzed structurally by X-ray single-crystal diffraction. X-ray crystallography data showed that the asymmetric unit of complex comprised an independent mononuclear cadmium complex with a seven-coordinate "CdN 4O2S" core. The complex was tested against four gram-positive and four gram-negative bacteria. It exhibited good activity against most of the bacteria and its activity was better than gentamicin as a standard antibiotic. The luminescence properties of the free ligand and the complex were investigated.© 2013 - IOS Press and the authors. All rights reserved.
Crystal structure, luminescence properties and biological studies of a novel polymeric cadmium II compound:[Cd (Clphtpy)(NCS)(NO 3)] n
NICOLO', Francesco;
2013-01-01
Abstract
The new 1D coordination polymer, [Cd(Clphtpy)(NCS)(NO3)] n (Clphtpy = 4'- chlorophenyl-2,2':6',2''-terpyridine), was prepared and characterized by CHN elemental analysis, 1H NMR-, IR spectroscopy and analyzed structurally by X-ray single-crystal diffraction. X-ray crystallography data showed that the asymmetric unit of complex comprised an independent mononuclear cadmium complex with a seven-coordinate "CdN 4O2S" core. The complex was tested against four gram-positive and four gram-negative bacteria. It exhibited good activity against most of the bacteria and its activity was better than gentamicin as a standard antibiotic. The luminescence properties of the free ligand and the complex were investigated.© 2013 - IOS Press and the authors. All rights reserved.Pubblicazioni consigliate
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