l,4-Benzodithians, when treated with bromine in anhydrous chlorofonn, undergo very fast monobromination at the aromatic ring. By the use of quantum mechanical semiempirical calculations, the reaction is shown to proceed most likely via a vicarious nucleophilic substitution of hydrogen.
Chemistry of ethanediyl S,S-acetals 6- An example of vicarious nucleophilic substitution of hydrogen in 1,4-benzodithians
DE NISCO, Mauro;
1993-01-01
Abstract
l,4-Benzodithians, when treated with bromine in anhydrous chlorofonn, undergo very fast monobromination at the aromatic ring. By the use of quantum mechanical semiempirical calculations, the reaction is shown to proceed most likely via a vicarious nucleophilic substitution of hydrogen.File in questo prodotto:
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