O-TBDPS D-glucosamine coupled with L-proline is reported to act as an efficient organocatalyst in the accomplishment of direct aldol reactions. Excellent results, in terms of chemical yields, as well as diastereomeric and enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone and acetone to variously substituted benzaldehydes.

D-Glucosamine in a chimeric prolinamide organocatalyst for direct asymmetric aldol addition

DE NISCO, Mauro;
2012

Abstract

O-TBDPS D-glucosamine coupled with L-proline is reported to act as an efficient organocatalyst in the accomplishment of direct aldol reactions. Excellent results, in terms of chemical yields, as well as diastereomeric and enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone and acetone to variously substituted benzaldehydes.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11570/3032784
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