Just the NMR spectrometer! An unprecedented NMR automatic titration of a water-soluble organometallic catalyst has been carried out without the use of any physical device employing instead the composite kinetic molecular device {[1.1.1]cryptand/imidazole}, capable of changing the pH and measuring it from inside the NMR tube.
{[1.1.1]Cryptand/Imidazole}: A Prototype Composite Kinetic Molecular Device for Automatic NMR Variable pH Reaction Monitoring
ALIBRANDI, Giuseppe;ARENA, Carmela;LANDO, GABRIELE;PARISI, Melchiorre
2011-01-01
Abstract
Just the NMR spectrometer! An unprecedented NMR automatic titration of a water-soluble organometallic catalyst has been carried out without the use of any physical device employing instead the composite kinetic molecular device {[1.1.1]cryptand/imidazole}, capable of changing the pH and measuring it from inside the NMR tube.File in questo prodotto:
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