A reactive azlactone-based graphene nanoplatform was successfully synthesized by the ligation of azido-azlactone with alkyne-terminated graphene via Cu(I)-catalyzed cycloaddition. The reactive azlactone rings, grafted on graphene sheets, were subjected to highly efficient ring-opening reactions with functionalized primary amine derivatives incorporating an aminosilane coupling agent or a biological fragment.

Engineering of carbon based nanomaterials by ring-opening reactions of a reactive azlactone graphene platform

NERI, GIULIA
Primo
;
SCALA, ANGELA
Secondo
;
BARRECA, Francesco;FAZIO, Enza;GRASSI, Giovanni
Penultimo
;
PIPERNO, Anna
Ultimo
2015-01-01

Abstract

A reactive azlactone-based graphene nanoplatform was successfully synthesized by the ligation of azido-azlactone with alkyne-terminated graphene via Cu(I)-catalyzed cycloaddition. The reactive azlactone rings, grafted on graphene sheets, were subjected to highly efficient ring-opening reactions with functionalized primary amine derivatives incorporating an aminosilane coupling agent or a biological fragment.
2015
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11570/3061830
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