Cationic rhodium(I) complexes containing the new chiral bidentate P,N ligand 2-[1-(1S,2S,5R)-(-)menthoxydiphenyl-phosphino]pyridine are prepared and used successfully in the enantioselective hydroformylation of olefinic substrates, styrene, 2-vinylnaphthalene, methylacrylate and vinylacetate.
Enantioselective hydroformylation with the chiral bidentate P,N-ligand 2-[1-(1S,2S,5R)-(-)menthoxydiphenylphosphino]pyridine cationic rhodium(I) complexes
NICOLO', Francesco;DROMMI, Dario;BRUNO, Giuseppe;FARAONE, Felice;ARENA, Carmela
1994-01-01
Abstract
Cationic rhodium(I) complexes containing the new chiral bidentate P,N ligand 2-[1-(1S,2S,5R)-(-)menthoxydiphenyl-phosphino]pyridine are prepared and used successfully in the enantioselective hydroformylation of olefinic substrates, styrene, 2-vinylnaphthalene, methylacrylate and vinylacetate.File in questo prodotto:
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