The relevance of neglecting three- and four-body interactions in the coarse-grained version of the Asakura–Oosawa model is examined. A mapping between the first few virial coefficients of the binary nonadditive hard-sphere mixture representative of this model and those arising from the coarse-grained (pairwise) depletion potential approximation allows for a quantitative evaluation of the effect of such interactions. This turns out to be especially important for large size ratios and large reservoir polymer packing fractions.
The effective colloid interaction in the Asakura–Oosawa model. Assessment of non-pairwise terms from the virial expansion
FIUMARA, GiacomoPenultimo
;
2015-01-01
Abstract
The relevance of neglecting three- and four-body interactions in the coarse-grained version of the Asakura–Oosawa model is examined. A mapping between the first few virial coefficients of the binary nonadditive hard-sphere mixture representative of this model and those arising from the coarse-grained (pairwise) depletion potential approximation allows for a quantitative evaluation of the effect of such interactions. This turns out to be especially important for large size ratios and large reservoir polymer packing fractions.File in questo prodotto:
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