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EnglishThe paper reports an unprecedented spectrophotometric determination of amines in chloroform, in which amines are not transformed into colored derivatives. This result has been achieved by exploiting the acid−base properties of the tight-ionpaired metal complexes [(HR2DTO)Pt(H2R2DTO)][Cl], which are able to donate a HCl molecule to an amine, giving rise to an ammonium salt and to the neutral complexes [(HR2DTO)2Pt]. The circumstance that [(HR2DTO)Pt(H2R2DTO)][Cl] and [(HR2DTO)2Pt] species show different absorptions in the visible region of the electromagnetic spectrum enables the aforementioned platinum complexes to behave as self-indicating titrants in the spectrophotometric determination of aliphatic amines, which are known to be UV−vis transparent. The new method has been tested by determining a series of fatty amines in the bulk and gave excellent results. The limits of applicability of this method (pKa > 4) were found by testing a series of benzodiazepines.
| Titolo: | Metal Complexes as Self-Indicating Titrants for Acid-Base Reactions in Chloroform |
| Autori: | LANZA, Santo (Ultimo) [Membro del Collaboration Group] |
| Data di pubblicazione: | 2018 |
| Rivista: | |
| Abstract: | The paper reports an unprecedented spectrophotometric determination of amines in chloroform, in which amines are not transformed into colored derivatives. This result has been achieved by exploiting the acid−base properties of the tight-ionpaired metal complexes [(HR2DTO)Pt(H2R2DTO)][Cl], which are able to donate a HCl molecule to an amine, giving rise to an ammonium salt and to the neutral complexes [(HR2DTO)2Pt]. The circumstance that [(HR2DTO)Pt(H2R2DTO)][Cl] and [(HR2DTO)2Pt] species show different absorptions in the visible region of the electromagnetic spectrum enables the aforementioned platinum complexes to behave as self-indicating titrants in the spectrophotometric determination of aliphatic amines, which are known to be UV−vis transparent. The new method has been tested by determining a series of fatty amines in the bulk and gave excellent results. The limits of applicability of this method (pKa > 4) were found by testing a series of benzodiazepines. |
| Handle: | http://hdl.handle.net/11570/3123469 |
| Appare nelle tipologie: | 14.a.1 Articolo su rivista |
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| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| acs.inorgchem.7b03081.pdf | Inorg. Chem. 2018, 57, 2175−2183.pdf | Versione Editoriale (PDF) | Tutti i diritti riservati (All rights reserved) | Administrator Richiedi una copia |
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