A novel bis-pillar[5]arene dicarboxylic acid self-assembles in the presence of 1,12-diaminododecane to yield overall neutral, internally ion-paired supramolecular polymers. Their aggregation, binding mode, and morphology can be tuned by external stimuli such as solvent polarity, concentration, and base treatment.
Stimuli-responsive internally ion-paired supramolecular polymer based on a bis-pillar[5]arene dicarboxylic acid monomer
A. NottiPrimo
;I. Pisagatti
Secondo
;F. Nastasi;S. Patanè;M. F. ParisiPenultimo
;G. Gattuso
Ultimo
2021-01-01
Abstract
A novel bis-pillar[5]arene dicarboxylic acid self-assembles in the presence of 1,12-diaminododecane to yield overall neutral, internally ion-paired supramolecular polymers. Their aggregation, binding mode, and morphology can be tuned by external stimuli such as solvent polarity, concentration, and base treatment.File in questo prodotto:
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J. Org. Chem. 2021, 86, 1676−1684.pdf
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