A diiminoisoindolo-pyrazino unit was annulated to the beta-pyrrolic position of the Zn complex of tetraphenylporphyrin, giving a macrocycle with an expanded pi system in satisfactory yields. The crystal structure of this derivative evidenced the formation of a hydrogen bond network. The interaction of the beta-fused isoindoline porphyrin derivative with nucleotides and nucleic acids has been investigated.
The interaction of a β-fused isoindoline–porphyrin conjugate with nucleic acids
Chiara M. A. Gangemi;
2016-01-01
Abstract
A diiminoisoindolo-pyrazino unit was annulated to the beta-pyrrolic position of the Zn complex of tetraphenylporphyrin, giving a macrocycle with an expanded pi system in satisfactory yields. The crystal structure of this derivative evidenced the formation of a hydrogen bond network. The interaction of the beta-fused isoindoline porphyrin derivative with nucleotides and nucleic acids has been investigated.File in questo prodotto:
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