Landfill leachate from Municipal Solid Waste: Multi-technique approach for its fine characterization and determination of the thermodynamic and sequestering properties towards some toxic metals

andfill leachate is a multicomponent aqueous matrix generated by the percolation of rainwater into the body of a landfill. Considering its content of natural and xenobiotic components, it must be considered as a waste, whose composition depends on type of waste, biodegradation processes, rainwater, composition and compaction of waste and their age; these factors influence the transport, absorption, toxicity, bioaccumulation of the contaminants. Leachates sampled from landfill and downhill piezometers, in periods characterized by different rainfall, were studied by ATR-FTIR and SEM-EDX techniques; analyses were carried out on dried and calcinated residues obtained at T = 383 and 923 K, respectively. The chemical-physical characterization of all the leachates was carried out by using the official methods of analysis, obtaining for many metals and some organic contaminants exceedance of the concentrations with respect to the limits established by the Italian Legislative Decree 152/2006. From potentiometric titrations carried out at T = 298.15 K in NaCl(aq) and applying the Polyprotic Like model, each leachate resulted to have a different composition in terms of COOH and OH groups and various acid-base properties. The interacting ability of leachates with metal cations (Cd2+, Zn2+, Cu2+) was studied by potentiometric and voltammetric (only for Pb2+) techniques in NaCl (NaNO3 for Pb2+) aqueous solutions, at I = 0.15 mol dm−3 and T = 298.15 K, obtaining diverse speciation models and complexes of very different stability. The leachates sequestering ability towards the metal cations was quantified at various pH values using the pL0.5 parameter, proving that each leachate has a different strength of interaction towards the metals, that tends to increase with the pH and confirming that they behave as carriers of contaminants through the soil and towards groundwater, with the consequent problems of contamination and/or environmental disaster and risks for the human health.