Convenient syntheses of TIPDS-Cl-2, and TBDMS-Br from the corresponding hydrides were obtained by using catalytic PdCl2 and CCl4 or CH2Br2, respectively. These systems can be successfully applied in tandem procedures for improved silylation Of nucleosides. (C) 1999 Elsevier Science Ltd. All rights reserved.
The PdCl2/R3SiH system for the silylation of nucleosides
ROMEO, Roberto;
1999-01-01
Abstract
Convenient syntheses of TIPDS-Cl-2, and TBDMS-Br from the corresponding hydrides were obtained by using catalytic PdCl2 and CCl4 or CH2Br2, respectively. These systems can be successfully applied in tandem procedures for improved silylation Of nucleosides. (C) 1999 Elsevier Science Ltd. All rights reserved.File in questo prodotto:
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