The title compound, [Ru(NO2)(2)(OH)(C10H8N2S)(NO)]. is the main product of the reaction between RuCl3? and dps (dps is 2,2'-dipyridyl sulfide, C10H8N2S) in ethanol-water at room temperature followed by reaction with NaNO2 at a higher temperature. The Ru atom has a distorted octahedral coordination geometry with the dps molecule behaving as an N,N'-bidentate ligand, The six-membered chelate ring adopts a boat conformation.
(2,2 '-Dipyridyl sulfide-N,N ')hydroxy-bis(nitrito-O)(nitrogen monoxide-N)-ruthenium(III)
BRUNO, Giuseppe;NICOLO', Francesco;TRESOLDI, Giuseppe
2000-01-01
Abstract
The title compound, [Ru(NO2)(2)(OH)(C10H8N2S)(NO)]. is the main product of the reaction between RuCl3? and dps (dps is 2,2'-dipyridyl sulfide, C10H8N2S) in ethanol-water at room temperature followed by reaction with NaNO2 at a higher temperature. The Ru atom has a distorted octahedral coordination geometry with the dps molecule behaving as an N,N'-bidentate ligand, The six-membered chelate ring adopts a boat conformation.File in questo prodotto:
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