The present contribution describes a research work focused on the elucidation of the composition of the headspace of Marsala wine. Four sample-types, of different ageing ("fine", "superiore secco", "superiore riserva", "vergine") were subjected to headspace solid-phase microextraction-comprehensive 2D GC analysis. At the outlet of the second GC dimension, the eluting analytes were split between a flame ionisation detector (for relative quantification purposes) and a rapid-scanning quadrupole mass spectrometer (for compound identification). Over 500 peaks were detected in each application, with a total of 128 compounds tentatively-identified considering the four sample types (mainly esters, alcohols, ketones, and aldehydes). The results attained open a door on the highly complex nature of the Marsala headspace; furthermore, they also demonstrated that the use of one-dimensional GC technologies, for the untargeted analysis of complex aroma profiles (e.g., dessert wines), is often too much of an analytical challenge. © 2013 Elsevier Ltd.

Elucidation of the volatile composition of Marsala wines by using comprehensive two-dimensional gas chromatography

DUGO, Giacomo;FRANCHINA, FLAVIO ANTONIO;BONACCORSI, Ivana Lidia;CICERO, Nicola;TRANCHIDA, Peter Quinto;MONDELLO, Luigi
2014

Abstract

The present contribution describes a research work focused on the elucidation of the composition of the headspace of Marsala wine. Four sample-types, of different ageing ("fine", "superiore secco", "superiore riserva", "vergine") were subjected to headspace solid-phase microextraction-comprehensive 2D GC analysis. At the outlet of the second GC dimension, the eluting analytes were split between a flame ionisation detector (for relative quantification purposes) and a rapid-scanning quadrupole mass spectrometer (for compound identification). Over 500 peaks were detected in each application, with a total of 128 compounds tentatively-identified considering the four sample types (mainly esters, alcohols, ketones, and aldehydes). The results attained open a door on the highly complex nature of the Marsala headspace; furthermore, they also demonstrated that the use of one-dimensional GC technologies, for the untargeted analysis of complex aroma profiles (e.g., dessert wines), is often too much of an analytical challenge. © 2013 Elsevier Ltd.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11570/2601170
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